Phlogiston Theory
In his awesome history of chemistry, Mendeleyev’s Dream , Paul Strathern has a chapter on phlogiston theory. In the 1600’s, Johann Becher postulated that all solids had 3 constituents: terra fluida (fluid component), terra lapida (solidifying element), and terra pinguis (combustible component). As per his theory, when wood is burnt, terra pinguis is released, leaving the ash. Georg Stahl extended the theory to state that terra pinguis could move from one thing to another, not just out of a substance during combustion. He also renamed it “phlogiston”. He said phlogiston explained combustion, smelting and rusting. Critics pointed out that combustion happened only in the presence of air, so why shouldn’t air be considered key to explaining combustion instead of this mysterious phlogiston? No, said Stahl, air was only the carrier of phlogiston from one thing to another. Others asked why phlogiston exchange caused fire during combustion but not during rusting? Stahl countered tha...